Production of biochar from rice straw and its application for wastewater remediation − An overview

The valorization of biochar as a green and low-cost adsorbent provides a sustainable alternative to commercial wastewater treatment technologies that are usually chemical intensive and expensive. This review presents an in-depth analysis focusing on the rice straw-derived biochar (RSB) for removal of various types of contaminants in wastewater remediation. Pyrolysis is to date the most established technology to produce biochar. Subsequently, biochar is upgraded via physical, chemical or hybrid activation/modification techniques to enhance its adsorption capacity and robustness. Thus far, acid-modified RSB is able to remove metal ions and organic compounds, while magnetic biochar and electrochemical deposition have emerged as potential biochar modification techniques. Besides, temperature and pH are the two main parameters that affect the efficiency of contaminants removal by RSB. Lastly, the limitations of RSB in wastewater remediation are elucidated based on the current advancements of the field, and future research directions are proposed

Progress in thermochemical co-processing of biomass and sludge for sustainable energy, value-added products and circular economy

To achieve the main goal of net zero carbon emission, the shift from conventional fossil-based energy/products to renewable and low carbon-based energy/products is necessary. Biomass has been perceived as a carbon–neutral source from which energy and value-added products can be derived, while sludge is a slurry waste that inherently contains high amount of minerals and organic matters. Hence, thermochemical co-processing of biomass wastes and sludge could create positive synergistic effects, resulting in enhanced performance of the process (higher conversion or yield) and improved qualities or characteristics of the products as compared to that of mono-processing. This review presents the current progress and development for various thermochemical techniques of biomass-sludge co-conversion to energy and high-value products, and the potential applications of these products from circular economy’s point of view. Also, these technologies are discussed from economic and environmental standpoints, and the outlook towards technology maturation and successful commercialization is laid out

Recent progress in the production and application of biochar and its composite in environmental biodegradation

Over the past few decades, extensive research has been conducted to develop cost-effective and high-quality biochar for environmental biodegradation purposes. Pyrolysis has emerged as a promising method for recovering biochar from biomass and waste materials. This study provides an overview of the current state-of-the-art biochar production technology, including the advancements and biochar applications in organic pollutants remediation, particularly wastewater treatment. Substantial progress has been made in biochar production through advanced thermochemical technologies. Moreover, the review underscores the importance of understanding the kinetics of pollutant degradation using biochar to maximize its synergies for potential environmental biodegradation. Finally, the study identifies the technological gaps and outlines future research advancements in biochar production and its applications for environmental biodegradation

Retrieving back plastic wastes for conversion to value added petrochemicals: opportunities, challenges and outlooks

Plastic production and its unplanned management and disposal, has been shown to pollute terrestrial, aquatic, and atmospheric environments. Petroleum-derived plastics do not decompose and tend to persist in the surrounding environment for longer time. Plastics can be ingested and accumulate into the tissues of both terrestrial and aquatic animals, which can impede their growth and development. Petrochemicals are the primary feedstocks for the manufacture of plastics. The plastic wastes can be retrieved back for conversion to value added petrochemicals including aromatic char, hydrogen, synthesis gas, and bio-crude oil using various technologies including thermochemical, catalytic conversion and chemolysis. This review focusses on technologies, opportunities, challenges and outlooks of retrieving back plastic wastes for conversion to value added petrochemicals. The review also explores both the technical and management approaches for conversion of plastic wastes to petrochemicals in regard to commercial feasibility, and economic and environmental sustainability. Further, this review work provides a detailed discussion on opportunities and challenges associated with recent thermochemical and catalytic conversion technologies adopted for retrieving plastic waste to fuels and chemicals. The review also recommends prospects for future research to improve the processes and cost-efficiency of promising technologies for conversion of plastic wastes to petrochemicals. It is envisioned that this review would overcomes the knowledge gaps on conversion technologies and further contribute in emerging sustainable approaches for exploiting plastic wastes for value-added products

Production of biochar from rice straw and its application for wastewater remediation − An overview

The valorization of biochar as a green and low-cost adsorbent provides a sustainable alternative to commercial wastewater treatment technologies that are usually chemical intensive and expensive. This review presents an in-depth analysis focusing on the rice straw-derived biochar (RSB) for removal of various types of contaminants in wastewater remediation. Pyrolysis is to date the most established technology to produce biochar. Subsequently, biochar is upgraded via physical, chemical or hybrid activation/modification techniques to enhance its adsorption capacity and robustness. Thus far, acid-modified RSB is able to remove metal ions and organic compounds, while magnetic biochar and electrochemical deposition have emerged as potential biochar modification techniques. Besides, temperature and pH are the two main parameters that affect the efficiency of contaminants removal by RSB. Lastly, the limitations of RSB in wastewater remediation are elucidated based on the current advancements of the field, and future research directions are proposed

Microwave processing of oil palm wastes for bioenergy production and circular economy: Recent advancements, challenges, and future prospects

The valorization and conversion of biomass into various value-added products and bioenergy play an important role in the realization of sustainable circular bioeconomy and net zero carbon emission goals. To that end, microwave technology has been perceived as a promising solution to process and manage oil palm waste due to its unique and efficient heating mechanism. This review presents an in-depth analysis focusing on microwave-assisted torrefaction, gasification, pyrolysis and advanced pyrolysis of various oil palm wastes. In particular, the products from these thermochemical conversion processes are energy-dense biochar (that could be used as solid fuel, adsorbents for contaminants removal and bio-fertilizer), phenolic-rich bio-oil, and H2-rich syngas. However, several challenges, including (1) the lack of detailed study on life cycle assessment and techno-economic analysis, (2) limited insights on the specific foreknowledge of microwave interaction with the oil palm wastes for continuous operation, and (3) effects of tunable parameters and catalyst's behavior/influence on the products’ selectivity and overall process's efficiency, remain to be addressed in the context of large-scale biomass valorization via microwave technology.</p

Pilot-scale co-processing of lignocellulosic biomass, algae, shellfish waste via thermochemical approach: Recent progress and future directions

Thermal co-processing of lignocellulosic and aquatic biomass, such as algae and shellfish waste, has shown synergistic effects in producing value-added energy products with higher process efficiency than the traditional method, highlighting the importance of scaling up to pilot-scale operations. This article discusses the design and operation of pilot-scale reactors for torrefaction, pyrolysis, and gasification, as well as the key parameters of co-processing biomass into targeted and improved quality products for use as fuel, agricultural application, and environmental remediation. Techno-economic analysis reveals that end product selling price, market dynamics, government policies, and biomass cost are crucial factors influencing the sustainability of thermal co-processing as a feasible approach to utilize the biomass. Because of its simplicity, pyrolysis allows greater energy recovery, while gasification has the highest net present value (profitability). Integration of liquefaction, hydrothermal, and fermentation pre-treatment technology has the potential to increase energy efficiency while reducing process residues.The authors would like to thank the Ministry of Higher Education, Malaysia under the HICOE Research Grant Scheme (UMT/CRIM/2-2/5 Jilid 2 (10), Vot. No. 56051 and UMT/CRIM/2-2/5 Jilid 2 (11), Vot. No. 56052), University of Technology Sarawak Research Grant (UCTS/RESEARCH/(01)) and HICoE AKUATROP Trust Account No. 66955 to perform this project. The work is also supported by Program for Innovative Research Team (in Science and Technology) in University of Henan Province (No. 21IRTSTHN020) and Central Plain Scholar Funding Project of Henan Province (No. 212101510005).Scopu